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ChemInform Abstract: New Synthesis of Spirocycles by Utilizing in situ Forming Hypervalent Iodine Species.

✍ Scribed by Toshifumi Dohi; Tomofumi Nakae; Yohei Ishikado; Daishi Kato; Yasuyuki Kita


Publisher
John Wiley and Sons
Year
2012
Weight
34 KB
Volume
43
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

The high‐yielding syntheses of cyclohexadienone‐type spirocyclic compounds with varied functionalities are achieved by a new and reliable one‐pot procedure.


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ChemInform Abstract: Hofmann Rearrangeme
✍ Aleksandra A. Zagulyaeva; Christopher T. Banek; Mekhman S. Yusubov; Viktor V. Zh πŸ“‚ Article πŸ“… 2011 πŸ› John Wiley and Sons βš– 41 KB πŸ‘ 1 views

## Abstract Carboxamides (I) react with in situ generated iodine(III) species and methanol to give carbamates (III) via Hofmann rearrangement.