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ChemInform Abstract: Hofmann Rearrangement of Carboxamides Mediated by Hypervalent Iodine Species Generated in situ from Iodobenzene and Oxone: Reaction Scope and Limitations.

✍ Scribed by Aleksandra A. Zagulyaeva; Christopher T. Banek; Mekhman S. Yusubov; Viktor V. Zhdankin


Publisher
John Wiley and Sons
Year
2011
Weight
41 KB
Volume
42
Category
Article
ISSN
0931-7597

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✦ Synopsis


Abstract

Carboxamides (I) react with in situ generated iodine(III) species and methanol to give carbamates (III) via Hofmann rearrangement.