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ChemInform Abstract: New Route to Functionalized Cyclohexenes from Nitromethane and Electrophilic Alkenes Without Solvent under Focused Microwave Irradiation.

✍ Scribed by D. MICHAUD; S. ABDALLAH-EL AYOUBI; M.-J. DOZIAS; L. TOUPET; F. TEXIER-BOULLET; J. HAMELIN

Publisher: John Wiley and Sons
Year: 2010
Weight: 31 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199752092

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✦ Synopsis

The title reaction affords two isomers of new cyclohexenes like (III) via a diastereoselective double Michael addition in the presence of a catalytic amount of piperidine. A stoichiometric amount of piperidine promotes the demethoxycarbonylation of compounds (III) to hexenes such as (IV). -

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