ChemInform Abstract: New Radical Allylation Reactions Using 2-Bromo-3-(phenylthio)propene and Their Application to the Synthesis of Carbocyclic Compounds.

✍ Scribed by B. YOO; D. P. CURRAN

• Publisher: John Wiley and Sons
• Year: 2010
• Weight: 36 KB
• Volume: 28
• Category: Article
• ISSN: 0931-7597
• DOI: 10.1002/chin.199724058

✦ Synopsis

New

Radical Allylation Reactions Using 2-Bromo-3-(phenylthio)propene and Their Application to the Synthesis of Carbocyclic Compounds.

-A new allyl transfer reagent, the title propene (III), is developed and utilized to prepare vinyl bromide precursors for radical cyclization reactions. These radical cyclizations provide a convenient and powerful method for the construction of a wide variety of carbocyclic compounds (cf. (VII), (XI)/(XII), (XV)/(XVI), (XIX)/(XX)). -(YOO, B.;