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ChemInform Abstract: New Mixed Rare-Earth Copper Oxochalcogenides with a LaOAgS-Type Structure.

✍ Scribed by D. O. Charkin; A. V. Akopyan; V. A. Dolgikh


Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis


copper, Cu copper, Cu I 7400

45 -032

New Mixed Rare-Earth Copper Oxochalcogenides with a LaOAgS-Type Structure.

-A series of new mixed oxochalcogenides of the general composition LnOCuX (Ln: Ce-Er, X: S, Se, Te; 9 examples) are prepared by solid state reactions of CuO, the corresponding chalcogen, and Ln and/or Ln 2 O 3 under optimized conditions. The new oxochalcogenides obtained crystallize in the tetragonal system analogously to LaOAgS. -(CHARKIN,


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ChemInform Abstract: Rare-Earth Mixed-Va
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Rare-Earth Mixed-Valence Vanadium Oxides with Superlattice Structures of Calcium Ferrite. -The novel compounds Ξ±-and Ξ²-YbV4O8 are prepared by solid state reaction of the binary oxides at 1973 and 1673 K, resp., and the structure of a single crystal of the Ξ±-phase and of a twinned one of the Ξ²-phase