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ChemInform Abstract: New Formal (3 + 2) Photoaddition of Vinyl Ethers to o-Benzoquinones.

โœ Scribed by A. TAKUWA; R. KAI; K. KAWASAKI; Y. NISHIGAICHI; H. IWAMOTO

Book ID
112036567
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
27
Category
Article
ISSN
0931-7597

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Photoaddition Reactions of o-Benzoquinones to 1,4-Diphenylbut-1en-3-yne: Formation of Phenanthrenes and Dihydrodioxins. -9-Phenylphenanthrenes (VI) or their precursors (V) are obtained from the photoreaction of o-benzoquinones (I) and enyne (II). Interestingly, the tetrabromo derivative (Ib) is mor