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ChemInform Abstract: Photoaddition Reactions of o-Benzoquinones to 1,4-Diphenylbut-1-en-3- yne: Formation of Phenanthrenes and Dihydrodioxins.

✍ Scribed by S. S. KIM; Y. J. MAH; A. R. KIM; D. J. YOO; S. C. SHIM


Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis


Photoaddition Reactions of o-Benzoquinones to 1,4-Diphenylbut-1en-3-yne: Formation of Phenanthrenes and Dihydrodioxins.

-9-Phenylphenanthrenes (VI) or their precursors (V) are obtained from the photoreaction of o-benzoquinones (I) and enyne (II). Interestingly, the tetrabromo derivative (Ib) is more efficient to give the phenanthrene (VIb). -(KIM, S.


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