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ChemInform Abstract: New Efficient and Stereoselective [2 + 2] Cycloadditions of Dimethylaluminum Enolates with Phenylvinylsulfoxide.

✍ Scribed by H. BIENAYME; N. GUICHER


Book ID
101851811
Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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High-Pressure Promoted Stereoselective Tandem [4 + 2]/[3 + 2] Cycloadditions of Nitroalkenes and Enol Ethers. -The tandem cycloadditions of the nitroalkenes (I) and (V) with ethyl vinyl ether are found to be strongly accelerated under high pressure. The reactions proceed regioand stereoselectively.