Ba3Te2O6X2 is obtained by reacting TeO2 in a BaX2 flux at 1000 Β°C under atmospheric conditions. The samples are characterized by powder and single crystal XRD. All four compounds crystallize in the cubic space group Fd3m with Z = 16. The structures consist of a rigid β 3 [M3Te2O6] 2+ framework (M: S
ChemInform Abstract: New Derivatives of the UCl3 Type of Structure. The Chlorides and Bromides M(SrSm)Cl6, M(SrEu)Cl6, and M(BaLa)X6 (M: Na, Ag; X: Cl, Br).
β Scribed by M. S. WICKLEDER; G. MEYER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0931-7597
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Action of Ammonium Chloride and Bromide on Vanadium, Niobium and Tantalum: Synthesis and Crystal Structures of (NH4)2(V(NH3)X5), (NH4)6( (M5(NH)4)X17) (M: Nb, Ta), (NH4)2(NbX6), and (NH4)3(Ta2NX10) (X: Cl, Br). -The reaction of NH4Cl or NH4Br with metallic V, Nb, and Ta at moderate temp. (320-430 β’
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