ChemInform Abstract: New Chalcogenogermanates with Adamantane Type Complex Anions: Preparation and Crystal Structures of K4Ge4S10; Rb4Ge4S10, Rb4Ge4Se10, and Cs4Ge4Se10.
β Scribed by Kurt O. Klepp; Ferdinand Fabian
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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## Abstract The title compound with approximate composition Na~4~Ge~7.68~Si~1.32~O~20~ is hydrothermally prepared from a GeO~2~/xH~2~O/5en/2βmethyl pentanethylenediamine/yNaSiO~3~Β·9H~2~O (x = 35β46; y = 0.1β0.5) mixture (autoclave, 160 Β°C, 7 d) and characterized by powder and single crystal XRD.