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ChemInform Abstract: Neovibsanines A and B, Unprecedented Diterpenes from Viburnum awabuki.

โœ Scribed by Y. FUKUYAMA; H. MINAMI; K. TAKEUCHI; M. KODAMA; K. KAWAZU

Book ID
112041709
Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
27
Category
Article
ISSN
0931-7597

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Neovibsanines A and B, unprecedented dit
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Neovibsanines A and B, isolated from the leaves of Viburnum awabuki, are unprecedented tricyclic diterpenoids, which are presumably biosynthesized via consecutive ring cleavage and cyclization from vibsanine B. Their relative structures have been established by extensive analysis of spectroscopic da

Neovibsanin C, a macrocyclic peroxide-co
Neovibsanin C, a macrocyclic peroxide-containing neovibsane-type diterpene from Viburnum awabuki
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A unique neovibsane-type diterpene, neovibsanin C (1), isolated from the leaves of Viburnum awabuki, has been demonstrated to have an unprecedented structure macrocyclized via an endo-peroxide by extensive analyses of spectral data and chemical degradation as well as synthesis of I from neovibsanin