Neovibsanin C, a macrocyclic peroxide-containing neovibsane-type diterpene from Viburnum awabuki

✍ Scribed by Miwa Kubo; Hiroyuki Minami; Eriko Hayashi; Mitsuaki Kodama; Kazuyoshi Kawazu; Yoshiyasu Fukuyama

• Book ID: 104261982
• Publisher: Elsevier Science
• Year: 1999
• Tongue: French
• Weight: 237 KB
• Volume: 40
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(99)01199-5

✦ Synopsis

A unique neovibsane-type diterpene, neovibsanin C (1), isolated from the leaves of Viburnum awabuki, has been demonstrated to have an unprecedented structure macrocyclized via an endo-peroxide by extensive analyses of spectral data and chemical degradation as well as synthesis of I from neovibsanin B (3).