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ChemInform Abstract: Neighboring Nucleophilic Group Assisted Rearrangement of Allylic Esters under Eu(fod)3 Catalysis.

✍ Scribed by Wei-Min Dai; Anxin Wu; Mavis Yuk Ha Lee; Kwong Wah Lai

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 33
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200213091

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✦ Synopsis

Abstract

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ChemInform Abstract: Eu(fod)3-Catalyzed

ChemInform Abstract: Eu(fod)3-Catalyzed Rearrangement of Allylic Esters Possessing a Chelating Site. Application to Enediyne Synthesis.

✍ Wei-Min Dai; Mavis Yuk Ha Lee 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 31 KB

Eu(fod) 3 -Catalyzed Rearrangement of Allylic Esters Possessing a Chelating Site. Application to Enediyne Synthesis. -1,2-Dialkynyl-3-alkyl or 3-aryl allylic esters (I) possessing a chelating site undergo Eu(fod) 3 -catalyzed rearrangement to yield cis-enediynes (II) exclusively (13 examples). The