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ChemInform Abstract: Natural Alkaloids and Synthetic Relatives as Chiral Templates of the Orito′s Reaction

✍ Scribed by Emilia Talas; Jozsef L. Margitfalvi

Publisher
John Wiley and Sons
Year
2010
Weight
15 KB
Volume
41
Category
Article
ISSN
0931-7597

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Synthetic Studies on Natural Products. Part 9. Chemoenzymatic Transformation of the Natural Antitumor Alkaloid 20-O-Acetylcamptothecin to Mappicine Ketone and (S)-Mappicine. -The naturally occurring alkaloid (I) is converted to mappicine ketone (V), an antiviral lead compound, and its natural reduc