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ChemInform Abstract: Multicomponent Reaction Design: A One-Pot Route to Substituted Di-O-acylglyceric Acid Amides from α-Diazoketones.

✍ Scribed by Lijun Fan; Ashley M. Adams; Bruce Ganem

Publisher: John Wiley and Sons
Year: 2009
Weight: 32 KB
Volume: 40
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200902058

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Abstract

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Multicomponent reaction design: a one-po

Multicomponent reaction design: a one-pot route to substituted di-O-acylglyceric acid amides from α-diazoketones

✍ Lijun Fan; Ashley M. Adams; Bruce Ganem 📂 Article 📅 2008 🏛 Elsevier Science 🌐 French ⚖ 154 KB

A four-component assembly of substituted di-O-acylglyceric acid amides has been developed from a-diazoketones. The process involves copper-catalyzed reaction of the a-diazoketone with a carboxylic acid, and subsequent Passerini condensation of the in situ formed a-acyloxyketone.