ChemInform Abstract: Modified Nucleosides. A General and Diastereoselective Approach to N,O-Psiconucleosides.
β Scribed by Daniela Iannazzo; Anna Piperno; Venerando Pistara; Antonio Rescifina; Roberto Romeo
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 30 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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π SIMILAR VOLUMES
Anomeric Ξ±and Ξ²-N,O-psiconucleosides were prepared by 1,3-dipolar cycloaddition of C-ethoxycarbonyl N-methyl nitrone with ethyl 2-acetyloxyacrylate, followed by VorbrΓΌggen nucleosidation. The synthetic scheme has been applied to all purine and pyrimidine nucleobases. Nucleosidation can proceed under