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ChemInform Abstract: Mo(CO)6/TBHP Catalyzed Autoxidation of 5-Alkylidene-4,5-dihydrofurans.

✍ Scribed by Alessandra Lattanzi; Patrizia Iannece; Arrigo Scettri

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199935121

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✦ Synopsis

Mo(CO) 6 /TBHP Catalyzed Autoxidation of 5-Alkylidene-4,5dihydrofurans. -Catalytic autoxidation of 5-alkylidene-4,5-dihydrofurans to give the corresponding hydroperoxides proceeds efficiently using Mo(CO) 6 /tbutyl hydroperoxide. The influence of different parameters such as solvent, temperature, oxygen and amount of catalyst is examined. In the presence of a radical scavenger, the oxidation is inhibited suggesting a radical mechanism.

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