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ChemInform Abstract: Mo(CO)6-Catalyzed One-Pot Conversion of Allyl Aryl Ethers to Dihydrobenzofurans.

✍ Scribed by A. M. BERNARD; M. T. COCCO; V. ONNIS; P. P. PIRAS

Publisher: John Wiley and Sons
Year: 2010
Weight: 27 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199723133

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✦ Synopsis

Mo(CO)6-Catalyzed One-Pot Conversion of Allyl Aryl Ethers to Dihydrobenzofurans. -Mo(CO)6 is found to be an effective catalyst for the tandem Claisen rearrangement-cyclization reaction of the allyl aryl ethers (I) and ( IV) to give dihydrobenzofurans (II) and (V) in good yield. In some cases, trace amounts of the corresponding phenols are observed as well.

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