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ChemInform Abstract: Migration of the Dibromophosphine Group - A Rare Example of 2,3- Isomerization in Pyrroles.

✍ Scribed by A. A. TOLMACHEV; T. E. TERIKOVSKAYA; S. P. IVONIN; A. A. CHAIKOVSKAYA

Book ID
112040717
Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
27
Category
Article
ISSN
0931-7597

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N β†’ C2 β†’ C3 migration of the dichloropho
N β†’ C2 β†’ C3 migration of the dichlorophosphino group in the synthesis of phosphorylated NH-pyrroles
✍ Aleksandra A. Chaikovskaya; Yurii V. Dmytriv; Nadiya V. Shevchuk; Radomyr V. Sma πŸ“‚ Article πŸ“… 2008 πŸ› John Wiley and Sons 🌐 English βš– 101 KB

## Abstract A successive N β†’ C~2~ β†’ C~3~ migration of the dichlorophosphino group has been found to occur in phosphorylation of unsubstituted pyrrole with phosphorus trichloride. As a result of this migration, a number of hitherto unknown C‐phosphorylated N‐unsubstituted pyrroles have been obtained