ChemInform Abstract: Microwave-Assisted Nickel(II) Acetylacetonate-Catalyzed Arylation of Aldehydes with Arylboronic Acids.
✍ Scribed by Wen Chen; Mostafa Baghbanzadeh; C. Oliver Kappe
- Publisher
- John Wiley and Sons
- Year
- 2011
- Weight
- 31 KB
- Volume
- 42
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract It provides an efficient access to a wide range of biaryls and polyarenes.
## Abstract **Ligand design by‐pam**: A ruthenium‐catalyzed asymmetric arylation of aldehydes with arylboronic acids has been developed, giving chiral diarylmethanols in good yields. The use of a chiral bidentate phosphoramidite ligand ((__R__,__R__)‐Me‐bipam) led to excellent enantioselectivities.
## Abstract **Lieber zweizähnig**: Die Titelreaktion liefert chirale Diarylmethanole in guten Ausbeuten. Mit dem chiralen zweizähnigen Phosphoramidit‐Liganden (__R__,__R__)‐Me‐bipam wurden mitunter ausgezeichnete Enantioselektivitäten erhalten.magnified image