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ChemInform Abstract: Me-Bipam for Enantioselective Ruthenium(II)-Catalyzed Arylation of Aldehydes with Arylboronic Acids.

✍ Scribed by Yasunori Yamamoto; Kazunori Kurihara; Norio Miyaura

Publisher
John Wiley and Sons
Year
2009
Weight
29 KB
Volume
40
Category
Article
ISSN
0931-7597

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Me-bipam for Enantioselective Ruthenium(
Me-bipam for Enantioselective Ruthenium(II)-Catalyzed Arylation of Aldehydes with Arylboronic Acids
✍ Yasunori Yamamoto; Kazunori Kurihara; Norio Miyaura 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 295 KB 👁 2 views

## Abstract **Ligand design by‐pam**: A ruthenium‐catalyzed asymmetric arylation of aldehydes with arylboronic acids has been developed, giving chiral diarylmethanols in good yields. The use of a chiral bidentate phosphoramidite ligand ((__R__,__R__)‐Me‐bipam) led to excellent enantioselectivities.

Me-bipam for Enantioselective Ruthenium(
Me-bipam for Enantioselective Ruthenium(II)-Catalyzed Arylation of Aldehydes with Arylboronic Acids
✍ Yasunori Yamamoto; Kazunori Kurihara; Norio Miyaura 📂 Article 📅 2009 🏛 John Wiley and Sons 🌐 English ⚖ 295 KB 👁 2 views

## Abstract **Lieber zweizähnig**: Die Titelreaktion liefert chirale Diarylmethanole in guten Ausbeuten. Mit dem chiralen zweizähnigen Phosphoramidit‐Liganden (__R__,__R__)‐Me‐bipam wurden mitunter ausgezeichnete Enantioselektivitäten erhalten.magnified image