𝔖 Bobbio Scriptorium
✦   LIBER   ✦

ChemInform Abstract: Mg2PN3 and Ca2PN3 - Phosphorus(V) Nitrides with Infinite Chains of Corner-Sharing PN4 Tetrahedra.

✍ Scribed by V. SCHULTZ-COULON; W. SCHNICK

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
28
Category
Article
ISSN
0931-7597

No coin nor oath required. For personal study only.

✦ Synopsis

Mg2PN3 and Ca2PN3 -Phosphorus(V) Nitrides with Infinite Chains of Corner-Sharing PN4 Tetrahedra.

-The title compounds are prepared by reaction of M3N2 (M: Mg , Ca) with P3N5 at 800 β€’ C (N2 atmosphere, 7 and 14 d, respectively). Mg2PN3 crystallizes in the orthorhombic space group Cmc21, Z = 4, and Ca2PN3 in space group Cmca, Z = 8 (powder XRD). Both compounds contain chains of corner-sharing PN4 tetrahedra; however, the chains significantly differ in their stretching factor. -(SCHULTZ-COULON,

πŸ“œ SIMILAR VOLUMES

Ca2PN3: A New Phosphorus(V) Nitride with
Ca2PN3: A New Phosphorus(V) Nitride with One-Dimensional Infinite Chains of Corner-Sharing PN4 Tetrahedra
✍ Priv.-Doz. Dr. Wolfgang Schnick; Dipl.-Chem. Verena Schultz-Coulon πŸ“‚ Article πŸ“… 1993 πŸ› John Wiley and Sons 🌐 English βš– 293 KB

Whether the enolate of biotin, produced on decarboxylation, functions as base for the deprotonation of the substrate, as discussed by J. R. Knowles,"] is unclear. In contrast to 5, propionylcarba(dethia)coenzyme A is actually carboxylated to its methylmalonyl derivative in the transcarboxylase react

High-Pressure Synthesis of Ξ³-P3N5 at 11
High-Pressure Synthesis of Ξ³-P3N5 at 11 GPa and 1500 Β°C in a Multianvil Assembly: A Binary Phosphorus(V) Nitride with a Three-Dimensional Network Structure from PN4 Tetrahedra and Tetragonal PN5 Pyramids
✍ Kai Landskron; Hubert Huppertz; JΓΌrgen Senker; Wolfgang Schnick πŸ“‚ Article πŸ“… 2001 πŸ› John Wiley and Sons 🌐 English βš– 101 KB πŸ‘ 1 views

allow the assignment of signals at d Γ€ 12 to the tetrahedral site and the one at d Γ€ 101 to the PN 5 pyramids.

ChemInform Abstract: Nd3NCl6 and Nd4NS3C
ChemInform Abstract: Nd3NCl6 and Nd4NS3Cl3: Two Derivatives of Neodymium Nitride with Discrete Units of Edge-Shared ([N2Nd6]12+) and Isolated [NNd4]9+ Tetrahedra, Respectively.
✍ Monika Meyer; Falk Lissner; Thomas Schleid πŸ“‚ Article πŸ“… 2010 πŸ› John Wiley and Sons βš– 32 KB πŸ‘ 1 views

## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable v