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Ca2PN3: A New Phosphorus(V) Nitride with One-Dimensional Infinite Chains of Corner-Sharing PN4 Tetrahedra

✍ Scribed by Priv.-Doz. Dr. Wolfgang Schnick; Dipl.-Chem. Verena Schultz-Coulon

Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
293 KB
Volume
32
Category
Article
ISSN
0044-8249

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✦ Synopsis

Whether the enolate of biotin, produced on decarboxylation, functions as base for the deprotonation of the substrate, as discussed by J. R. Knowles,"] is unclear. In contrast to 5, propionylcarba(dethia)coenzyme A is actually carboxylated to its methylmalonyl derivative in the transcarboxylase reaction.[121

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ChemInform Abstract: Mg2PN3 and Ca2PN3 -
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Mg2PN3 and Ca2PN3 -Phosphorus(V) Nitrides with Infinite Chains of Corner-Sharing PN4 Tetrahedra. -The title compounds are prepared by reaction of M3N2 (M: Mg , Ca) with P3N5 at 800 β€’ C (N2 atmosphere, 7 and 14 d, respectively). Mg2PN3 crystallizes in the orthorhombic space group Cmc21, Z = 4, and C

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allow the assignment of signals at d Γ€ 12 to the tetrahedral site and the one at d Γ€ 101 to the PN 5 pyramids.