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ChemInform Abstract: Metal-Free Direct Amidation of Peptidyl Thiol Esters with α-Amino Acid Esters.

✍ Scribed by Hao Chen; Maomao He; Yaya Wang; Linhui Zhai; Yongbo Cui; Yangyan Li; Yan Li; Haibing Zhou; Xuechuan Hong; Zixin Deng

No coin nor oath required. For personal study only.

✦ Synopsis

A protocol for the direct amidation of peptidyl thiol esters promoted by bis(trimethylsilyl)acetamide is presented.

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## Abstract A novel low toxic, water‐ and air‐tolerated method under mild and neutral conditions for the title reaction is developed.