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ChemInform Abstract: Metal-Catalyzed Carbocyclization by Intramolecular Reaction of Allylsilanes and Allylstannanes with Alkynes.

✍ Scribed by Carolina Fernandez-Rivas; Maria Mendez; Antonio M. Echavarren

Publisher: John Wiley and Sons
Year: 2010
Weight: 35 KB
Volume: 31
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200020054

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The Reaction of Polyhalides with Allylsilanes Catalyzed by Copper(I) Chloride. -Allyltrimethylsilane (I) reacts with polyhalogen compounds (II) in the presence of copper species affording polyhalo compounds containing an allyl group. Other allylsilanes, e.g. (IV), (VI), and (IX), give various produ