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ChemInform Abstract: Mechanism of Photochemical Rearrangements of 3-Substituted Cyclopropenes to Cyclopentadienes.

โœ Scribed by M.-D. SU

Book ID
112028189
Publisher
John Wiley and Sons
Year
2010
Weight
26 KB
Volume
27
Category
Article
ISSN
0931-7597

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During the course of our studies dealing with the photochemical transformations of small ring compounds, we uncovered an unusual substituent effect on the mode of ring opening of an unsymmetrically substituted cyclopropene. 192 Thus, the major product obtained from the irradiation of 1 was derived f