ChemInform Abstract: Mechanism of Nucleophilic Attack on 1- and 2-Bromo(π-allyl)palladium Complexes.
✍ Scribed by M. G. ORGAN; M. MILLER; Z. KONSTANTINOU
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 37 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Both 1-and 2-Bromo(πallyl)palladium Complexes. -The regioselectivity of the nucleophilic attack of phenolates (II) to π-allyl(Pd) complexes generated from 1,3-and 2,3-dibromopropenes (I) and (V) are examined. The formation of (III) from the 1,3-dibromo derivative (I) involves a primarily attack at
k: Vricfc. J. C'/iiwi. S o ( . C/imi. C ' o i ) i i i i i i i i . 1976. 64: h) .I Kuyper. I. k: V r i c ~c . J. Org:aiioiiii,/ C / w i i i . 1976. 116. 1. I). Stdlks. .I O r , q i i i i i ~i i i e ~/ . ('/wiii. 1991. 4/R. 127: h) S. Freitap. W, Kolod/iqski. t'. P:iuer. D. Stalks. .I. C/iiwi. S i c .
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