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ChemInform Abstract: New Reactions Involving Palladacyclobutanes: The Attack of Phenoxide Ion at the Central Carbon of Both 1- and 2-Bromo(π-allyl)palladium Complexes.

✍ Scribed by M. G. ORGAN; M. MILLER

Publisher
John Wiley and Sons
Year
2010
Weight
33 KB
Volume
29
Category
Article
ISSN
0931-7597

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✦ Synopsis

Both 1-and 2-Bromo(πallyl)palladium Complexes.

-The regioselectivity of the nucleophilic attack of phenolates (II) to π-allyl(Pd) complexes generated from 1,3-and 2,3-dibromopropenes (I) and (V) are examined. The formation of (III) from the 1,3-dibromo derivative (I) involves a primarily attack at the central carbon of the allyl complex. Interestingly, both substrates react with sodium dimethyl methyl malonate (VI) at the terminal positions exclusively. -(ORGAN, M.

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