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ChemInform Abstract: Mechanism of Electron Transfer Oxidation of 4-Substituted 1-Benzyl-1,4- dihydronicotinamides

โœ Scribed by N. TAKADA; S. ITOH; S. FUKUZUMI

Book ID
112042348
Publisher
John Wiley and Sons
Year
2010
Weight
25 KB
Volume
28
Category
Article
ISSN
0931-7597

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Electron-transfer chain-substitution in
Electron-transfer chain-substitution in hydrodemercuration of alkylmercury(II) compounds with n-benzyl-1,4-dihydronicotinamide
โœ Hideo Kurosawa; Hiroshi Okada; Tatsuaki Hattori ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 216 KB

Reduction of alkylmercury(I1) acetates with N-benzyl-1,4\_dihydronicotin amide (BNAH) proceeds through electron-transfer chain-substitution mechanism. The rate constant of hydrogen transfer from BNAH to alkyl radical was estimated as in the order of lo5 l/mol.sec. There is much current interest bo