ChemInform Abstract: Magnesium Bis(diisopropylamide), a Useful Reagent for Regio- and Stereoselective Synthesis of Kinetic Silyl Enol Ethers.
β Scribed by Guillaume Lessene; Regis Tripoli; Philippe Cazeau; Claude Biran; Michel Bordeau
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 29 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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Bis[bis(methylthio)lithiomethyl]dimethylsilanes: A Useful Reagent for the Synthesis of Polysilacarbacycles via Disilylation. -The lithiated title compound (I) is a novel reagent for the synthesis of polysilacarbacycles such as (III) or (V) through a dianionic ring-closure strategy. The two sulfenyl