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ChemInform Abstract: Bis[bis(methylthio)lithiomethyl]dimethylsilanes: A Useful Reagent for the Synthesis of Polysilacarbacycles via Disilylation.

✍ Scribed by M. SHIMIZU; M. IWAKUBO; Y. NISHIHARA; T. HIYAMA

Publisher: John Wiley and Sons
Year: 2010
Weight: 32 KB
Volume: 29
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199832220

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✦ Synopsis

Bis[bis(methylthio)lithiomethyl]dimethylsilanes: A Useful Reagent for the Synthesis of Polysilacarbacycles via Disilylation.

-The lithiated title compound (I) is a novel reagent for the synthesis of polysilacarbacycles such as (III) or (V) through a dianionic ring-closure strategy. The two sulfenyl groups play a key role in stabilization of the dilithiated silane and can be easily removed.

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