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ChemInform Abstract: Lipase-Catalyzed Asymmetric Desymmetrization of Prochiral 2,2-Disubstituted 1,3-Propanediols Using 1-Ethoxyvinyl Benzoate.

✍ Scribed by Shuji Akai; Tadaatsu Naka; Yasushi Takebe; Yasuyuki Kita

Publisher
John Wiley and Sons
Year
2001
Weight
31 KB
Volume
32
Category
Article
ISSN
0931-7597

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Enzyme-Catalyzed Asymmetrization of 2,2-Disubstituted 1,3-Propanediols Using 1-Ethoxyvinyl Esters. -The lipase-mediated asymmetrization of prochiral diols using various 1-ethoxyvinyl esters (I) is studied. The benzoate ester (Ia) provides good to excellent chemical yields and the highest enantiosel