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ChemInform Abstract: Enzyme-Catalyzed Asymmetrization of 2,2-Disubstituted 1,3-Propanediols Using 1-Ethoxyvinyl Esters.

✍ Scribed by S. AKAI; T. NAKA; Y. TAKEBE; Y. KITA

Publisher
John Wiley and Sons
Year
2010
Weight
29 KB
Volume
28
Category
Article
ISSN
0931-7597

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✦ Synopsis

Enzyme-Catalyzed Asymmetrization of 2,2-Disubstituted 1,3-Propanediols Using 1-Ethoxyvinyl Esters.

-The lipase-mediated asymmetrization of prochiral diols using various 1-ethoxyvinyl esters (I) is studied. The benzoate ester (Ia) provides good to excellent chemical yields and the highest enantioselectivities. -(AKAI, S.

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