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ChemInform Abstract: LiAl(OC(Ph)(CF3)2)4: A Hydrocarbon-Soluble Catalyst for Carbon-Carbon Bond-Forming Reactions.

✍ Scribed by T. J. BARBARICH; S. T. HANDY; S. M. MILLER; O. P. ANDERSON; P. A. GRIECO; S. H. STRAUSS

Publisher: John Wiley and Sons
Year: 2010
Weight: 36 KB
Volume: 28
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199701053

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✦ Synopsis

LiAl(OC(Ph)(CF3)2)4: A Hydrocarbon-Soluble Catalyst for Carbon-Carbon Bond-Forming Reactions.

-LiAl(OC(Ph)(CF3)2)4, which is generated from LiAlH4 and HOC(CF3)2Ph, is found to be an efficient catalyst for the 1,4-conjugate addition of silyl ketene acetals to α,β-unsaturated carbonyl compounds and for the direct substitution of allylic acetals by silyl ketene acetals. -(BARBARICH, T.

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