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ChemInform Abstract: Binaphthol-Derived Phosphoric Acid as a Versatile Catalyst for Enantioselective Carbon—Carbon Bond Forming Reactions

✍ Scribed by Masahiro Terada


Publisher
John Wiley and Sons
Year
2009
Weight
15 KB
Volume
40
Category
Article
ISSN
0931-7597

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LiAl(OC(Ph)(CF3)2)4: A Hydrocarbon-Soluble Catalyst for Carbon-Carbon Bond-Forming Reactions. -LiAl(OC(Ph)(CF3)2)4, which is generated from LiAlH4 and HOC(CF3)2Ph, is found to be an efficient catalyst for the 1,4-conjugate addition of silyl ketene acetals to α,β-unsaturated carbonyl compounds and f