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ChemInform Abstract: Lewis Acid Catalyzed Rearrangement/Reduction of 1- Phenyloxiranemethanamines: Synthesis of β-Phenethylamines.

✍ Scribed by R. C. HARDEN; T. J. HODGKINSON; A. MCKILLOP; W. G. PROWSE; M. W. J. URQUHART

Publisher
John Wiley and Sons
Year
2010
Weight
38 KB
Volume
28
Category
Article
ISSN
0931-7597

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✍ L. CASARRUBIOS; J. A. PEREZ; M. BROOKHART; J. L. TEMPLETON 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 28 KB 👁 1 views

Lewis Acid Catalyzed Synthesis of Aziridines. -A convenient synthesis of the title compounds becomes possible in the presence of Lewis acids. The enamines (VI) and (VII), formed as by-products, can be easily removed by SiO2 chromatography. AlCl3 or TiCl4 generally give similar results.