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ChemInform Abstract: Kinetic and Thermodynamic Approaches for the Efficient Formation of Mechanical Bonds

✍ Scribed by William R. Dichtel; Ognjen S. Miljanic; Wenyu Zhang; Jason M. Spruell; Kaushik Patel; Ivan Aprahamian; James R. Heath; J. Fraser Stoddart

Publisher: John Wiley and Sons
Year: 2009
Weight: 15 KB
Volume: 40
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200916263

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## Abstract We have developed novel fluorogenic transformations based on formation of CC bonds catalyzed by palladium using iodocoumarin **1** as a model aryl iodide, where fluorescence is quenched completely due to effects of the heavy, polarizable iodine atom. Substitution of the iodine atom for