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ChemInform Abstract: Josiphos-Catalyzed Asymmetric Homodimerization of Ketoketenes.

✍ Scribed by Ahmad A. Ibrahim; Pei-Hsun Wei; Gero D. Harzmann; Nessan J. Kerrigan

Publisher
John Wiley and Sons
Year
2011
Weight
43 KB
Volume
42
Category
Article
ISSN
0931-7597

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## Abstract The reaction applies catalytic amounts of Pd(OAc)~2~ and Cu(OTf)~2~ under oxygen atmosphere to afford symmetrical 2,2‐disubstituted biaryls that display a wide range of amide functionality and tolerates ortho‐, meta‐ and para substitution at the biphenyl rings.