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ChemInform Abstract: Investigation of Heterodimeric and Homodimeric Radical Cations of the Series: [F2O2]+, [F2Cl2]+, [Cl2O2]+, [F4]+, and [Cl4]+.

✍ Scribed by Tobias Schloeder; Sebastian Riedel

Book ID: 112043578
Publisher: John Wiley and Sons
Year: 2012
Weight: 19 KB
Volume: 43
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201218001

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Rate constants for the reaction of CN( u= 0) with Cl,, FZ and O2 have been measured. CN radicals were generated by photolysis of C2Nz with pulsed radiation at 193 nm. Laser-induced fluorescence (LIF) was used to monitor the decay profiles of CN radical concentrations. The valuesobtainedare: k(CN/CI?