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ChemInform Abstract: Invention of Radical Reactions. Part 33. Homologation Reactions of Carboxylic Acids by Radical Chain Chemistry.

โœ Scribed by D. H. R. BARTON; C.-Y. CHERN; J. CS. JASZBERENYI


Book ID
112023003
Publisher
John Wiley and Sons
Year
2010
Weight
32 KB
Volume
26
Category
Article
ISSN
0931-7597

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The invention of radical reactions: Part
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Irradiation with visible light of N-hydraxy-2-thiopyridone esters f in the presence of sulphur dioxidrgave the corresponding th~os~fp~o~otes 4 in good yiefd. These could be converted to s&phones 5 by-treatment with KOH and an alkylating ogent. Alternatively, exposure to sulphuryl chloride followed b