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ChemInform Abstract: Intramolecular Trapping of Amides by 1-Lithio-1-bromocyclopropanes.

✍ Scribed by Mark S. Baird; Florian A. M. Huber; Viacheslav V. Tverezovsky; Ivan G. Bolesov

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
32
Category
Article
ISSN
0931-7597

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✦ Synopsis

Abstract

ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a β€œFull Text” option. The original article is trackable via the β€œReferences” option.

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Synthesis of Carbocycles by Insertion of 1,1-Dihalo-1-lithio Species into Zirconacycles. -Selected halogenocarbenoids insert into a zirconacyclopentane to produce the related five-membered carbocyclic rings [cf. (III)] via sequential 1,2-metalate and diotropic rearrangements. Extension of this meth