ChemInform Abstract: Palladium-Catalyzed
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W. OPPOLZER; A. PIMM; B. STAMMEN; W. E. HUME
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Article
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2010
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John Wiley and Sons
⚖ 37 KB
Palladium-Catalyzed Intramolecular Cyclization of Olefinic Propargylic Carbonates and Application to the Diastereoselective Synthesis of Enantiomerically Pure (-)-α-Thujone. -Pd/P(2-furyl)3 catalyzed title reactions afford intermediate palladium( alkenyl)bicyclo(3.1.0)hexanes, which can be trapped