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ChemInform Abstract: Intramolecular Cycloaddition Reactions of ω-Unsaturated Chiral Nitrones.

✍ Scribed by J. MARCUS; J. BRUSSEE; A. VAN DER GEN


Publisher
John Wiley and Sons
Year
2010
Weight
36 KB
Volume
30
Category
Article
ISSN
0931-7597

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Intramolecular Cycloaddition Reactions o
✍ Jan Marcus; Johannes Brussee; Arne van der Gen 📂 Article 📅 1998 🏛 John Wiley and Sons 🌐 English ⚖ 151 KB

The intramolecular 1,3-dipolar cycloaddition of ω-unmolecular cycloaddition, followed by reductive opening of the isoxazolidine ring, produced five-and seven-membered saturated chiral nitrones is described. Starting materials for this reaction are O-protected chiral cyanohydrins, prepared ring compo