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ChemInform Abstract: Chiral Nitrone Reagents for Cycloaddition Reactions

✍ Scribed by Raymond C. F. Jones; Jason N. Martin; Paul Smith


Publisher
John Wiley and Sons
Year
2000
Weight
24 KB
Volume
31
Category
Article
ISSN
0931-7597

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Intramolecular Cycloaddition Reactions o
✍ Jan Marcus; Johannes Brussee; Arne van der Gen πŸ“‚ Article πŸ“… 1998 πŸ› John Wiley and Sons 🌐 English βš– 151 KB

The intramolecular 1,3-dipolar cycloaddition of Ο‰-unmolecular cycloaddition, followed by reductive opening of the isoxazolidine ring, produced five-and seven-membered saturated chiral nitrones is described. Starting materials for this reaction are O-protected chiral cyanohydrins, prepared ring compo