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ChemInform Abstract: Intramolecular Copper- and Rhodium-Mediated Carbenoid Reactions of α-(Propargyloxy)silyl-α-diazoacetates.

✍ Scribed by Volker Gettwert; Fred Krebs; Gerhard Maas

Publisher: John Wiley and Sons
Year: 2010
Weight: 36 KB
Volume: 30
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.199932177

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Intramolecular Copper- and Rhodium-Media

Intramolecular Copper- and Rhodium-Mediated Carbenoid Reactions of α-(Propargyloxy)silyl-α-diazoacetates

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Copper(I) triflate catalyzes the transformation of α-[(2experimental observations are explained in terms of metalmediated intramolecular cyclopropenation and subsequent alkynyl)oxy]silyl-α-diazoacetates 1a-g into 1,2-bis(2,5dihydro-1,2-oxasilol-4-yl)ethenes 2 and/or 2H-1,2-oxasilines metal-assisted

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v

ChemInform Abstract: Anomalous Products

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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v