ChemInform Abstract: Silicon-Tethered 1,3-Dipolar Cycloaddition Reactions of Unsaturated α-Silyl-α-diazoacetates and Diazoacetic Acid Silyl Esters.
✍ Scribed by Gerhard Maas; Volker Gettwert
- Publisher
- John Wiley and Sons
- Year
- 2000
- Weight
- 39 KB
- Volume
- 31
- Category
- Article
- ISSN
- 0931-7597
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📜 SIMILAR VOLUMES
Part 3. Photoreactions of α,β-Unsaturated γ,δ-Epoxy Dinitrile, α-Cyano Ester, and Diester with Various Dipolarophiles. -Photolysis of the dinitrile (I) generates a carbonyl ylide which undergoes 1,3-dipolar cycloaddition with enol ethers [cf. (II)] to give cycloadducts (III) and (IV) in low yields.
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