ChemInform Abstract: Intramolecular Conjugate Addition Reactions of Amines and Carbamates to 2,5-Cyclohexadien-1-ones: Stereoselective Synthesis of Perhydroindoles.
β Scribed by Douglas Bland; Gilles Chambournier; Vladimir Dragan; David J. Hart
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 35 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
Perhydropyrrolo(1,2-a)indole Synthesis: Diastereoselection in an Intramolecular Conjugate Addition of an Amine to a 1,4-Cyclohexadienone. -The cyclization of the chiral aminocyclohexadienone (S)-(X) occurs with high diastereoselectivity affording the perhydroindole (XII). This reaction may be used
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
Application to the Enantioselective Synthesis of (-)-Isoretronecanol and (+)-Laburnine. -Compound (I) is an adduct of a stereoselective radical addition of a tertiary amine with (5R)-5-menthyloxy-2[5H]-furanone. It is readily transformed to (+)-laburnine (IV) in a three-step sequence. Similarly, (-
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v