## Abstract The Rh‐catalyzed asymmetric addition of α‐ (VII) or β‐substituted S‐chelating aldehydes (I), (V) towards terminal alkynes (II) is successfully used as kinetic resolution procedure to afford the corresponding α‐ and β‐substituted enones in up to 90% optical purity.
ChemInform Abstract: Intermolecular Rhodium-Catalyzed Hydroacylation of Allenes: The Regioselective Synthesis of β,γ-Unsaturated Ketones.
✍ Scribed by Helen E. Randell-Sly; James D. Osborne; Robert L. Woodward; Gordon S. Currie; Michael C. Willis
- Publisher
- John Wiley and Sons
- Year
- 2009
- Weight
- 37 KB
- Volume
- 40
- Category
- Article
- ISSN
- 0931-7597
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v
## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 200 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable v