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ChemInform Abstract: Intermolecular Alkyl/Aryl Exchange of 2-Iminothiazoles with Isothiocyanates and Isocyanates: Scopes and Limitations.

✍ Scribed by Dongyun Shin; Jihoon Lee; Hoh-Gyu Hahn

Publisher: John Wiley and Sons
Year: 2010
Weight: 49 KB
Volume: 41
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.201047124

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1,3-Thiazepines. Part 2. Reaction of 2-Iminohexahydrothiazepines with Phenyl Isocyanate and Isothiocyanates. -Reaction of the iminothiazepines (I) with phenyl isocyanate (II) gives the expected ureas (III) in good yields. In contrast, reaction with aryl isothiocyanates in refluxing toluene produces