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ChemInform Abstract: Intermolecular Addition of α-Boryl Radicals.

✍ Scribed by R. A. BATEY; B. PEDRAM; K. YONG; G. BAQUER


Publisher
John Wiley and Sons
Year
2010
Weight
31 KB
Volume
28
Category
Article
ISSN
0931-7597

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## Generation of α-Boryl Radicals by Reduction of α-Haloalkylboronic Esters with CrCl 2 . -Reduction of α-haloakylboronic esters (I) under optimized conditions generates α-boryl radicals, which readily react with electron-deficient olefins to yield the adducts (III) under mild conditions. -