ChemInform Abstract: Intermolecular Addition of α-Boryl Radicals.
✍ Scribed by R. A. BATEY; B. PEDRAM; K. YONG; G. BAQUER
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 31 KB
- Volume
- 28
- Category
- Article
- ISSN
- 0931-7597
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## Generation of α-Boryl Radicals by Reduction of α-Haloalkylboronic Esters with CrCl 2 . -Reduction of α-haloakylboronic esters (I) under optimized conditions generates α-boryl radicals, which readily react with electron-deficient olefins to yield the adducts (III) under mild conditions. -